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师资队伍

 

姓名:赵长伟

性别:女

职称:教授

Email: zhaocw@cau.edu.cn

办公室:资环楼二区324


教育背景


2001.02 - 2003.12 天津大学   化工学院    工学博士

1998.09 - 2001.01 沈阳化工大学 化学工程学院  工学硕士

1994.09 - 1998.07 沈阳化工大学 化学工程学院  工学学士


工作履历


2019.09 – 至今   中国农业大学资源与环境学院    教授

2017.01 – 2019.09 中国科学院生态环境研究中心    研究员

2013.09 – 2014.03 哈佛大学工程与应用科学院      访问学者

2008.03 – 2016.12 中国科学院生态环境研究中心    副研究员

2006.11 – 2008.02 中国科学院生态环境研究中心    助理研究员

2005.11 – 2006.11 法国科学院               博士后

2004.03 – 2005.11 清华大学                 博士后


学术兼职


北京膜学会       副秘书长、常务理事                  

中国海洋学会海水淡化与水再利用分会青年专家委员会 委员


研究领域


1. 水处理技术

2. 环境功能材料

3. 新型持久性有机污染物控制


奖励与荣誉


1. 黑龙江省技术发明一等奖

2. 第八届“侯德榜化工科学技术青年奖”

3. 中国科学院青年创新促进会首批优秀会员

4. 中国科学院卢嘉锡青年人才奖

5. 中国科学院青年创新促进会首批会员


主持项目


1. 十四五”国家重点研发计划项目,水系统安全保障策略与关键技术研究

2. 国家自然科学基金,全氟辛酸/重金属复合污染物的纳滤去除效能及微观作用机制研究

3. 国防重点基金,面向放射性废水高效分离的新型碳基修饰纳滤膜材料研发及性能研究

4.“十四五”国家重点研发计划项目,微生物降解高效复合菌剂及自动装置研发

5. 国家自然科学基金,饮用水中内分泌干扰物的纳滤截留效能及界面过程研究

6. 国家科技支撑计划课题,村镇饮用水净化处理工艺材料及设备开发

7. 国家科技支撑计划课题,村镇既有水厂改造关键技术与工艺集成示范

8. 国家高技术研究发展计划(863计划)课题,新型膜材料及膜组器的制备和应用关键技术与工程示范

9. 国家高技术研究发展计划(863计划)课题,新型芳香聚酰胺类中空纳滤膜除污染技术


学术成果


一、发表论文

2022年:

1. Wenjing Tang, Yunyi Meng, Bin Yang, Dongyu He, Yan Li, Bojun Li, Zheming Shi,  Changwei Zhao*. 2022. Preparation of hollow-fiber nanofiltration membranes of high performance for effective removal of PFOA and high resistance to BSA fouling. Journal of Environmental Sciences, 122: 14-24.

2. 赫东煜, 李研, 王钰琪, 张悦, 郑承银, 赵长伟*. 2022. 放射性废水典型核素去除研究进展. 现代化工(待发表).

3. 赵英海, 唐文晶, 赫东煜, 李研, 赵长伟*, 江荣风. 2022.土地渗滤系统与膜分离系统组合处理农村生活污水研究. 水处理技术(待发表).

4. 史哲明, 郭琳, 莫锐, 范贝贝, 赵长伟*. 2022. 微生物修复多环芳烃污染土壤的研究进展. 现代化工(待发表).


2021年:

1. Changwei Zhao*, Yi Xu, Feng Xiao, Jun Ma, Yubin Zou, Wenjing Tang. 2021. Perfluorooctane sulfonate removal by metal-organic frameworks (MOFs): Insights into the effect and mechanism of metal nodes and organic ligands. Chemical Engineering Journal, 406:126852.

2. Lixue Liu, Ling Yu, Baoleerhu Borjigin, Qinyi Liu, Changwei Zhao, Deyin Hou*. 2021. Fabrication of thin-film composite nanofiltration membranes with improved performance using β-cyclodextrin as monomer for efficient separation of dye/salt mixtures. Applied Surface Science, 539: 148284.

3. 赵长伟*, 唐文晶, 贾文娟, 李研, 赫东煜, 史哲民, 宋瑞平.  2021. 纳滤去除水中新兴污染物的研究进展. 膜科学与技术, 41(1):8.

4. 黄俊亮, 刘成, 王胜涛, 赵长伟, 邱超, 陈卫*.  2021. 离子交换工艺对地表水中硝酸盐的去除效能及应用模式. 给水排水, 47(11):8.


2020年:

1. Changwei Zhao*, Tong Zhang, Guangshuo Hu, Jun Ma, Ruiping Song, Jiding Li. 2020. Efficient removal of perfluorooctane sulphonate by nanofiltration: Insights into the effect and mechanism of coexisting inorganic ions and humic acid. Journal of Membrane Science, 610(6):118176.

2. Changwei Zhao*, Tingting Song, Yang Yu, Laiye Qu, Jinxing Cheng, Wenkai Zhu, Qingbo Wang, Pei Li, Wenjing Tang. 2020. Insight into the influence of humic acid and sodium alginate fractions on membrane fouling in coagulation-ultrafiltration combined system. Environmental Research, 191:110228.

3. Baoleerhu Borjigin, lixue Liu,Ling Yu,Lili Xu,Changwei Zhao*, Jun Wang. 2020. Influence of incorporating beta zeolite nanoparticles on water permeability and ion selectivity of polyamide nanofiltration membranes. Journal of Environmental Sciences, 98: 77-84.

4. 刘丽雪, 张少峰*, 赵长伟*,俞灵,宝乐尔呼,王军. 2020. β-环糊精为水相单体的复合纳滤膜制备及染料截留性能. 化工学报, 71(2):10.

5. 刘晓环, 张少峰*, 赵长伟*, 俞灵刘丽雪王军. 2020. 掺杂石墨相氮化碳高通量芳香聚酰胺超滤膜制备. 水处理技术, 46(1):6.


2019年:

1. Deyin Hou*, Chunli Ding, Chaochen Fu, Dewu Wang, Changwei Zhao, Jun Wang*. 2019. Electrospun nanofibrous omniphobic membrane for anti-surfactant-wetting membrane distillation desalination. Desalination, 468: 114068.

2. Yanjun Zhang,Changwei Zhao*, Shaofeng Zhang*, Ling Yu,Jiding Li,Li-an Hou. 2019. Preparation of SGO-modified nanofiltration membrane and its application in SO42− and Cl separation in salt treatment. Journal of Environmental Sciences, 78: 183-192.

3. Yangjun Zhang, Shaofeng Zhang*, Changwei Zhao*, Jun Wang. 2019. Preparation of Sulfonated Graphene Oxide Modified Composite Nanofiltration Membrane and Application in Salts Separation. 40(2): 724-729.

4. 张彦君, 张少峰*, 赵长伟, 王军. 2019. SGO改性复合纳滤膜的制备及分盐性能. 环境科学, 40(2),724-729.


2018:

1. Changwei Zhao, Bin Yang, Jinglong Han, Yunyi Meng, Ling Yu, Deyin Hou*,Jun Wang, Ying Zhao, Yonghong Zhai, Shuguang Wang, Xuefei Sun. 2018. Preparation of carboxylic multiwalled-carbon-nanotube-modified poly(m-phenylene isophthalamide) hollow fiber nanofiltration membranes with improved performance and application for dye removal. Applied Surface Science, 453(30): 502-512.

2. Changwei Zhao, Guangshuo Hu, Deyin Hou*, Ling Yu, Ying Zhao*, Jun Wang, Aixin Cao, Yonghong Zhai. 2018. Study on the effects of cations and anions on the removal of perfluorooctane sulphonate by nanofiltration membrane. Separation and Purification Technology, 202:385-396.


2017:

1. Mei Yang, Changwei Zhao*, Shaofeng Zhang*, Pei Li, Deyin Hou. 2017. Preparation of graphene oxide modified poly(m-phenylene isophthalamide) nanofiltration membrane with improved water flux and antifouling property. Applied Surface Science, 394(1):149-159.

2. Xipeng Li, Changwei Zhao*, Mei Yang, Bin Yang, Deyin Hou, Tao Wang. 2017. Reduced graphene oxide-NH2modified low pressure nanofiltration composite hollow fiber membranes with improved water flux and antifouling capabilities. Applied Surface Science, 419(15): 418-428.

3. Deyin Hou, Dichu Lin, Changwei Zhao*, Jun Wang, Chaochen Fu. 2017. Control of protein (BSA) fouling by ultrasonic irradiation during membrane distillation process. Separation and Purification Technology, 175(24):287-297.

4. Xiaohui Zhang, Quangeng Li, Jun Wang*, Jie Li, Changwei Zhao, Deyin Hou. 2017. Effect of feed solution pH and draw solution concentration on the performance of phenolic compounds removal in forward osmosis. Journal of Environmental Chemical Engineering, 5(3):2508-2514.


2016:

1. Changwei Zhao*, Jing Fan, Dong Chen, Yi Xu, Tao Wang. 2016. Microfluidics-generated graphene oxide microspheres and their application in perfluorooctane sulfonate removal from polluted water. Nano Research, 9(3):866-875.

2. Changwei Zhao*, Chuyang Tang, Pei Li, Pegoraro Adrian, Guangshuo Hu. 2016. Perfluorooctane sulfonate removal by nanofiltration membrane-the effect and interaction of magnesium ion / humic acid. Journal of Membrane Science, 503:31-41.

3. Yang Yu, Changwei Zhao*, Ling Yu, Pei Li, Tao Wang, Yi Xu. 2016. Removal of perfluorooctane sulfonates from water by a hybrid coagulation-nanofiltration process. Chemical Engineering Journal, 289: 7-16.

4. Qin Luo, Changwei Zhao*, Guixia Liu, Hao Ren. 2016. A porous aromatic framework constructed from benzene rings has a high adsorption capacity for perfluorooctane sulfonate. Scientific Reports, 20311:1-9.

5. Jinglong Han, Xue Xia, Yu Tao, Hui Yun, Yanan Hou, Changwei Zhao, Qin Luo, Haoyi Cheng, Aijie Wang*. 2016. Shielding membrane surface carboxyl groups by covalent-binding graphene oxide to improve anti-fouling property and the simultaneous promotion of flux. Water Research,102: 619-628.

6. Qin Luo, Yanxia Liu, Guixia Liu*, Changwei Zhao*. 2016. Preparation, characterization and performance of poly(m-phenylene isophthalamide)/organically modified montmorillonite nanocomposite membranes in removal of perfluorooctane sulfonate. Journal of Environmental Sciences, 46:126-133.

7.  Deyin Hou*, Lijuan Zhang, Changwei Zhao, Hua Fan, Jun Wang, Hongjing Huang. 2016. Ultrasonic irradiation control of silica fouling during membrane distillation process. Desalination, 386(16):48-57.

8. Jin Wang, Changwei Zhao, Tao Wang, Zhen Wu, Xiang Li, Jiding Li*. 2016. Graphene oxide polypiperazine-amide nanofiltration membrane for improving flux and anti-fouling in water purification. RSC Advabces, 6(85):82174-82185.


2015:

1. Tao Wang, Changwei Zhao*, Pei Li, Ye Li, Jun Wang. 2015. Fabrication of novel poly(m-phenylene isophthalamide) hollow fiber nanofiltration membrane for effective removal of trace amount perfluorooctane sulfonate from water. Journal of Membrane Science, 477:74-85.

2. Tao Wang, Changwei Zhao*, Pei Li, Ye Li, Jun Wang. 2015. Effect of non-solvent additives on the morphology and separation performance of poly(m-phenylene isophthalamide) (PMIA) hollow fiber nanofiltration membrane. Desalination, 365:293-307.

3. Tao Wang, Ye Li, Changwei Zhao*. 2015. Synthesis and Properties of high oil absorptive cross-linked lauryl acrylate-styrene-egdma copolymers. Fresenius Environmental Bulletin, 24:2460-2469.

4. 王涛, 李烨, 马文瑾, 张健, 赵长伟*, 王军.  2015.  PMIA中空纤维纳滤膜去除饮用水中的PFOS. 水处理技术, 41(7):103-108.


2013:

1. Changwei Zhao*, Jian Zhang, Guangzhi He, Tao Wang, Deyin Hou, Zhaokun Luan. 2013. Perfluorooctane sulfonate removal by nanofiltration membrane-the role of calcium ions. Chemical Engineering Journal, 233( 11): 224-232.

2. Yang Yu, Changwei Zhao*, Yangui Wang, Weihong Fan, Zhaokun Luan. 2013. Effects of ions concentration and natural organic matter on the arsenic (Ⅴ) removal by nanofiltration under different transmembrane pressures. Journal of Environmental Sciences, 25(2): 302-307.

3. 张健, 赵长伟*, 宋娜, 王涛, 栾兆坤.  2013. 纳滤去除饮用水中PFOS. 环境工程学报, 7(11):4236-4240.

4. 王艳贵, 赵长伟*, 于洋, 黄占斌, 冯园园.  2013. 有机物组成对混凝-纳滤组合工艺的影响.环境工程, 31(1):292-295.

5. 宋娜*, 章丽萍, 张健, 王涛, 赵长伟. 2013. 浊度对混凝-纳滤组合工艺的影响. 环境工程, 31(S1):28-31.

6. 于洋, 赵长伟*, 王艳贵, 范卫红, 栾兆坤. 2013. 絮体性质对纳滤膜污染的影响.环境工程学报, 7(2):427-432.


2012年:

1. Changwei Zhao*, Xiaonian Wang, Jinsong He, Yuanyuan Wang, Zhaokun Luan. 2012. Effect of polyethylene glycol on the properties of γ-Al2O3 formation by polyaluminum chloride. Chinese Journal of Chemical Engineering, 20(5) 1034-1038.

2. Changwei Zhao*, Songshan Du, Tao Wang, Jian Zhang, Zhaokun Luan. 2012. Arsenic removal from drinking water by self-made PMIA nanofiltration membrane. Advances in Chemical Engineering and Science, 2(3)20830.

3. Changwei Zhao, Yong Yan,Deyin Hou,Zhaokun Luan*,Zhiping Jia. 2012. Preparation of high concentration polyaluminum chloride by chemical synthesis-membrane distillation method with self-made hollow fiber membrane. Journal of Environmental Sciences, 24(5):834-839.

4.  Changwei Zhao,YongYan, ChuyiZeng, HongZhao, TaoWang, ZhaokunLuan*. 2012. Effect of mixed SiO2 nanoparticle/TiO2 sol on structure and performance of PVDF composite membranes. Fresenius Environmental Bulletin, 21(10): 2859-2865.

5. 杜嵩山*, 赵长伟, 任晓晶, 栾兆坤, 贾智萍. 2012. 纳滤膜去除饮用水中Cr()的应用研究. 中国给水排水, 28(23):82-84.

6. 任晓晶, 赵长伟, 张忠国*, 栾兆坤, 程言君, 李继定. 2012. 聚酰胺非对称纳滤膜在印染废水深度处理中的应用. 水处理技术, 38(3):67-70.

7. 王园园, 赵长伟*, 何劲松, 闫勇, 张香兰, 栾兆坤. 2012. 聚合氯化铝制备拟薄水铝石及 γ-Al2O3的研究Ⅱ—表面活性剂影响探讨. 无机化学学报, 28(2):302-306.

8. 闫勇, 赵长伟*, 曾楚怡, 张琳, 王圆圆, 栾兆坤. 2012. 混合溶剂对TiO2/PVDF平板超滤膜性能和结构的影响. 水处理技术, 38(1):27-31.


2011年:

1. Changwei Zhao*, Jun Wang, Zhaokun Luan. 2011. Preparation of high concentration polyaluminum chloride with high Alc content by membrane distillation. Chinese Journal of Chemical Engineering, 19(1):173-176.

2. Fan Ni, Changwei Zhao, Yiran Li, Ta Wang, Jie Tong, Jinsong He, Jun Wang, Zhaokun Luan*. 2011. Study on selenite removal by polyaluminum chloride and polyferric sulfate. Chinese Journal of Environmental Engineering, 5(11): 2401-2404.

3. 范卫红, 赵长伟*, 秦培勇, 王军, 于洋, 栾兆坤. 2011. 水中螺旋霉素的分光光度法快速检测. 环境化学, 30(12):2106-2107.

4. 闫勇, 赵长伟*, 曾楚怡, 栾兆坤. 2011. γ-Al2O3/TiO2混合纳米粒子改性PVDF超滤膜. 化工进展, 30(12):2665-2670.

5. 王涛, 李烨, 赵长伟*, 倪帆, 何劲松, 栾兆坤. 2011. 饮用水源水无机金属污染的应急处理. 环境工程学报, 5(12):2707-2711.

6. 倪帆, 赵长伟*, 李亦然, 王涛, 佟洁, 何劲松, 王军, 栾兆坤. 2011. 聚合氯化铝和聚合硫酸铁对水中亚硒酸盐的去除研究. 环境工程学报, 5(11):2401-2404.

7. 闫勇, 赵长伟*, 曾楚怡, 于洋, 栾兆坤.  2011. 混合添加剂对TiO2/PVDF平板超滤膜性能和结构的影响. 水处理技术, 37(09):68-72.

8. 闫勇, 赵长伟*, 曾楚怡, 王涛, 栾兆坤. 2011. TiO2纳米粒子对PVDF超滤膜的结构与性能影响研究. 水处理技术, 37(08):35-39.


2010年:

1. Jun Wang, Xianjia Peng*, Zhaokun Luan, Changwei Zhao.  2010. Regeneration of carbon nanotubes exhausted with dye reactive red 3BS using microwave irradiation. Journal of Hazardous Materials, 178(01):1125-1127.

2. Deyin Hou*,Jun Wang,Xiangcheng Sun, Zhaokun Luan, Changwei Zhao, Xiaojing Ren. 2010. Boron removal from aqueous solution by direct contact membrane distillation. Journal of Hazardous Materials, 177(1-3):613-619.

3. Deyin Hou*, Jun Wang, Changwei Zhao, Baoqiang Wang, Zhaokun Luan,Xiangcheng Sun. 2010. Fluoride removal from brackish groundwater by direct contact membrane distillation. Journal of Environmental Sciences, 22(12):1860-1867.

4. Changwei Zhao*, Xiaonian Wang, Jinsong He, Zhaokun Luan, Xianjia Peng, Zhiping Jia. 2010. Preparation and characterization ofγ-Al2O3 by polyaluminum chloride with high Al13 content. Chinese Journal of Chemical Engineering, 18(2): 333-336.

5. Deyin Hou, Jun Wang*, Changwei Zhao, Baoqiang Wang, Zhaokun Luan, Xiangcheng Sun. 2010. Fluoride removal from brackish groundwater by direct contact membrane distillation. Journal of Environmental Sciences, 22(12):1860-1867.

6. 赵长伟*, 杜嵩山, 王涛, 栾兆坤, 贾智萍. 2010. 纳滤去除饮用水中三卤甲烷的研究. 第四届中国膜科学与技术报告会论文集, 665-667.

7. 侯得印*, 王军, 栾兆坤, 赵长伟, 孙项城, 王宝强, 王涛. 2010. 新型PVDF中空纤维疏水复合膜制备与表征. 第四届中国膜科学与技术报告会论文集, 345-352.

8. 王涛, 李烨, 赵长伟, 侯得印*, 任晓晶, 栾兆坤. 2010. /湿相转化法制备芳香聚酰胺纳滤膜及其对水中染料的去除研究. 第四届中国膜科学与技术报告会论文集, 357-362.

9. 何劲松, 赵长伟*, 屠梦波, 倪帆, 王涛, 栾兆坤. 2010. 聚合氯化铝制备球形拟薄水铝石和γ-Al2O3的研究Ⅰ—制备条件探讨. 无机化学学报, 26(09): 1533-1538.

10. 赵长伟, 何劲松, 任晓晶, 栾兆坤*, 王军, 贾智萍. 2010. 聚合氯化铝制备拟薄水铝石及其性质研究. 无机化学学报, 26(03):521-524.


2009:

1. Changwei Zhao, Jingbo Zhang, Zhaokun Luan*, Xianjia Peng, Xiaojing Ren. 2009. Preparation of high concentration polyaluminum chloride with high content of Alb or Alc. Journal of Environmental Sciences, 21(10):1342-1346.

2. Jianjun JiaXianjia PengZhaokun LuanBin FanJun WangChangwei Zhao*. 2009. Removal of dyes from water by carbon nanotubes. Fresenius Environmental Bulletin,18(5), 615-618.

3. Dan Qu,Jun Wang,Deyin Hou,Zhaokun Luan*,Bin Fan,Changwei Zhao. 2009. Experimental study of arsenic removal by direct contact membrane distillation. Journal of hazardous materials, 163(2-3): 874-879.

4. Yujie Guo*, Guoting Li, Changwei Zhao, Qingling Zhao, Jun Wang, Zhaokun Luan . 2009. High-concentration epsilon-Al-13 nanoclusters sol prepared by chemical synthesis and membrane distillation concentration process. Separation and Purification Technology, 69(2):221-223.

5. Changwei Zhao*, Jiding Li, Jian Chen, Rongbin Qi,Zhaokun Luan.2009. Separation of Sulfur/Gasoline Mixture with Polydimethylsiloxane/Polyetherimide Composite Membranes by Pervaporation. Chinese Journal of Chemical Engineering, 17(4):707-710.

6. 王丽, 任晓晶, 赵长伟, 栾兆坤*. 2009. 新型芳香聚酰胺纳滤膜制备过程影响因素探讨. 水处理技术, 35(7):38-41.

7. 贾建军, 赵长伟*, 张静波, 栾兆坤, 武洁玮, 刘成蹊. 2009. 高浓度高Alb含量聚合氯化铝的制备及其水解行为研究. 无机化学学报, 25(2):5.


2008:

1. Changwei Zhao*,Jiding Li,Rongbin Qi,Jian Chen,Zhaokun Luan.2008. Pervaporation separation of n-heptane/sulfur species mixtures with polydimethylsiloxane membranes. Separation and purification technology, 63(1): 220-225.

2. 郭宇杰*, 贾智萍, 赵长伟, 王军, 栾兆坤, 范彬. 2008. 膜吸收过程中吸收液膨胀的产生及抑制方法. 环境化学,  27(6):4.


2007:

1. 陈天泉, 陈金勋, 李继定*, 赵长伟, 陈翠仙. 2007. 正庚烷/有机硫体系渗透汽化脱硫. 膜科学与技术, 27(4):5.


2006年:

1. Rongbin Qi, Yujun Wang, Jiding Li*, Changwei Zhao, Shenlin Zhu. 2006. Pervaporation separation of alkane/thiophene mixtures with PDMS membrane. Journal of Membrane Science, 280(1-2):545-552.

2. Changwei Zhao,Jiding Li*,Chuyi Zeng. 2006. Determination of the infinite dilution diffusion and activity coefficients of alkanes in polypropylene by inverse gas chromatography. Journal of Applied Polymer Science, 101(3):1925-1930.

3. Changwei Zhao, Jiding Li*, Zhen Jiang, Cuixian Chen. 2006. Measurement of the infinite dilution diffusion coefficients of small molecule solvents in silicone rubber by inverse gas chromatography. European Polymer Journal, 42(3):615-624.

4. Rongbin Qi, Changwei Zhao, Jiding Li*, Yujun Wang, Shenlin Zhu. 2006. Removal of thiophenes from n -octane/thiophene mixtures by pervaporation. Journal of Membrane Science, 269(1-2):94-100.

5. Chuyi Zeng, Jiding Li*, Ding Wang, Tianquan Chen, Changwei Zhao, Cuixian Chen. 2006. Infinite Dilute Activity and Diffusion Coefficients in Polymers by Inverse Gas Chromatography. Journal of Chemical and Engineering Data, 51(1): 93-98.

6. 赵长伟, 李继定*, 赵之平, 亓荣彬 陈翠仙, 于宏伟, 张志华. 2006. PDMS 有机硅膜的制备及其渗透汽化脱硫的研究. 膜科学与技术, 26(5).


二、授权专利:

1. 赵长伟; 李希鹏; 张盼盼; 徐毅. 一种低压正电荷中空纤维纳滤膜的制备方法. 201510847583.6.

2. 赵长伟; 杨梅; 杨彬. 一种聚间苯二甲酰间苯二胺纳滤膜的制备方法. 201510846215.X.

3. 赵长伟; 李继定; 赵之平; 陈翠仙. 一种渗透汽化汽油脱硫共混复合膜及其制备方法. 200510011355.1.

4. 宋婷婷; 赵长伟. 一种在线研究膜界面行为的方法. 201310476434.4.

5. 栾兆坤; 何劲松; 赵长伟.一种利用聚合氯化铝制备球形氧化铝的方法. 201010156085.4.


三、出版著作

1.     《纳滤水处理技术》北京:科学出版社, 2022, 参编.

2.     《中国水处理行业可持续发展战略研究报告膜工业卷》北京:中国人民大学出版社, 2013, 参编.